Steps:
- Make the brine: Place the chicken in a gallon-size Ziploc bag. In a blender, combine, pickle juice, water, habanero pepper, salt and sugar, and mix on medium speed until smooth. Pour the brine over the chicken and seal the bag. Chill for 4 to 8 hours.
- Remove the chicken from the brine and lay the thighs in a single layer, skin-sides up, on a wire rack set over a rimmed baking sheet. Chill, uncovered, for 1 hour.
- Make the hot chicken: In a large bowl, combine the flour, paprika, cayenne, salt and black pepper. Dredge the chicken thighs in the seasoned flour, then pat them between your hands to shake off excess. Return the chicken to the wire rack, reserving the seasoned flour, and chill another 30 minutes.
- Meanwhile, make the spicy oil: In a large saucepan, combine the cayenne, smoked and sweet paprika, cumin, garlic powder, salt and sugar. Place over medium heat and toast until fragrant, stirring often, 2 minutes. Slowly add the oil and heat for 10 minutes, then remove from the heat and keep warm. Make ahead: Let the oil cool to room temperature, then store in the fridge, covered, for up to 2 weeks.
- Dredge the chicken thighs in the reserved flour once more and return them to the wire rack. Chill in the fridge for a final 30 minutes.
- Line a clean rimmed sheet tray with a clean wire rack and set aside. Attach a deep-fry thermometer to a large cast-iron skillet, and fill it with oil to a ½-inch depth. Place the skillet over medium-high heat until a thermometer registers 365°. Working in 2 batches, lay the chicken thighs in the hot oil, skin-sides down and away from you, and cook until the bottoms are deep golden brown, 5 to 6 minutes. Carefully flip and continue to cook until the each chicken thigh is deep brown, and a meat thermometer inserted into the deepest part of the thigh registers 160°, another 6 minutes. Transfer the chicken to the wire rack and repeat with the remaining thighs.
- Using a large slotted spoon, dunk the fried chicken into the hot oil, turning to coat both sides.
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