Steps:
- Position a rack in the center of the oven and preheat the broiler.
- Poke small slits in the sausages with a paring knife to prevent them from bursting during cooking. Transfer to a rimmed baking sheet.
- Seed the bell peppers, if using, and cut into strips. Leave any Italian long hots and mini peppers whole. Transfer to the baking sheet.
- Trim the tops from any scallions. Cut any red onions into wedges. Quarter any shallots and halve any cippolini. Transfer to the baking sheet.
- Drizzle the sausages and vegetables with 1/4 cup of the olive oil and season with salt and pepper. Toss to combine.
- Broil on the center rack until the vegetables are golden and charred and the sausages are cooked through, tossing every 5 minutes and rotating the baking sheet to ensure even cooking, 15 to 20 minutes.
- Meanwhile, combine the pepperoncini, pepperoncini brine, fire-roasted red bell peppers, mustard, parsley, sugar and the remaining 2 tablespoons olive oil in a small bowl. Stir to combine. Season with salt and pepper.
- Congrats, it's time to plate! For each serving, place 1 sausage and some of the broiled peppers and onions in a shallow bowl. Top with some of the pepper relish. Serve with crusty bread or rice. Enjoy!
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