Steps:
- Combine first 5 ingredients. Place 2 T mixture in a blender. Set aside remaining mixture. Remove 2 chiles and 2 T sauce from can; add to blender. Add 1 C chopped onion and next 3 ingredients to blender; process smooth. Combine brisket and chipotle mixture in zip-top plastic bag; seal. Marinate in refrigerator 24 hours, turn occasionally. Soak wood chunks in water 16 hours; drain. Remove brisket from bag, pat dry, and rub with remaining sugar mixture. Let stand 30 minutes. Remove grill rack and prepare grill for indirect grilling, heating one side to medium-low and leaving one side with no heat. Maintain temperature at 225°. Pierce bottom of disposable aluminum foil pan several times with the tip of knife. Place pan on heated side of grill; add half of wood chunks. Place another foil pan (do not pierce pan) on unheated side. Pour 2 C water in pan. Coat grill rack with cooking spray and place on grill. Place brisket on rack over foil pan on unheated side. Close lid; cook 3.5 hours or until meat thermometer registers 170°. Add additional wood chunks halfway during cooking. Preheat oven to 250°. Remove brisket from grill. Place sliced onion and jalapeño on large sheet of foil. Top with brisket; seal tightly. Place brisket in large baking pan. Bake at 250° for 1.5 hours or until thermometer registers 190°. Remove from oven. Let stand, wrapped, 1 hour. Unwrap brisket, reserving juices; trim and discard fat. Cut brisket across grain into thin slices. To prepare sauce, finely chop sliced onion and jalapeño; set aside. Place brisket juices in zip-top plastic bag inside 2-cup glass measure; let stand 10 minutes (fat will rise to the top). Seal bag; carefully snip off bottom corner of bag. Drain 1/2 C drippings into saucepan, stopping before fat layer reaches opening; discard fat and remaining drippings. Add onion, jalapeño, broth, and remaining ingredients to pan; cook over medium heat 5 minutes or until thoroughly heated.
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