Steps:
- For the pears: Lightly butter a 9 inch round cake pan, line bottom with parchment paper and butter paper. Put the butter, brown sugar, lemon zest and juice in a large skillet. Cook over med heat, stirring, until melted. Add the pears, cover and simmer, turning once, until the pears are soft and juicy, about 4 minutes. Pour the pears and their syrup into a strainer set over a saucepan. Set the syrup and 1 pear quarter aside. Arrange pears in pan 1/4 inch from sides, with stem ends towards center and rounded sides down. Chop reserved pear and place pieces in center just enough to fill. Set aside. For the cake: Set a rack in the middle of the oven and preheat to 350. Scald milk in a small saucepan; keep warm. Whisk flour with almonds, soda, baking powder, salt, cinnamon and cloves. Beat butter with an electric mixer at med speed until smooth, about 2 minutes. Increase speed to med-high and gradually add granulated sugar; continue beating until mixture i light and fluffy, about 4 minutes, scraping down sides of bowl. Add cocoa powder and vanilla and beat 1 minute. While mixing at med-low speed, add eggs one at a time, beating well after each addition. While mixing slowly, add flour mixture in 4 additions; turn off mixer and fold in the hot milk with a rubber spatula. Spread the batter over the pears, taking care not to disturb them. Tap the pan lightly on the counter to settle the batter. Bake until a toothpick inserted in the center comes out clean, about 50 minutes. Cool cake in the pan on a wire rack for 20 minutes, then invert the cake onto a serving plate. Cool briefly, carefully peel the parchment paper from the top, and then cool completely. To finish the cake: Boil the reserved pear syruo until slightly thick and lightly brush the top of the cake. Whisk a few tbs of cocoa powder with an equal amount of confectioner's sugar and sift over the cake.
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